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Medical Forum / General / Nutrition / December 2007

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Chocolate bubble bursting

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Taka - 24 Dec 2007 04:26 GMT
Damn manufacturers, they are taking the best out of it without even
bothering to mention this on the labels ...

The Problem With Chocolate

Most people have heard that chocolate is good for you. But now, the
medical journal Lancet is bursting the chocolate bubble.
Just in time for the holidays, a Lancet editorial published today
notes that there won't be a "truffle treatment" for heart disease any
time soon. In fact, the editors point out that the very thing that
makes chocolate good for you -- the antioxidants called flavanols -
also make chocolate taste bitter. As a result, confectionery makers
often take out the flavanols, stripping the chocolate of its main
health-promoting properties. Worse, labels usually don't tell you
whether your chocolate comes with or without flavanols, making it
tough to know if a particular piece of chocolate has any health
benefits at all.
This depressing news comes just a month after Circulation, the medical
journal for the American Heart Association, created a stir when it
reported a study of 22 heart transplant patients who were given a dose
of dark chocolate or fake chocolate. Just two hours after eating the
real thing, patients had measurable improvements in blood flow and
vascular function and less clotting, compared to placebo chocolate
eaters, who experienced no changes.
The Circulation report is the latest in a string of studies touting
the benefits of chocolate. The flavonoids in chocolate, which include
the antioxidants called flavanols, are similar to those found in tea,
red wine and some fruits and vegetables, foods also known for their
heart-healthy effects.
To boost your chances of getting a flavanol-rich bar, the best bet is
to look for very dark chocolate with few added ingredients, notes Dr.
Jacob Shani, chairman of the Cardiac Institute at Maimonides Medical
Center in Brooklyn, NY.
The darker the chocolate, the higher it's likely to be in flavonoids,
according to the February issue of Mayo Clinic Health Letter. A
typical bar of dark chocolate contains an average of 53.5 milligrams
of flavonoids. A milk chocolate bar contains less than 14 milligrams,
while white chocolate doesn't have any, according to the Mayo report.
But even if your chocolate is loaded with flavanols, it won't be a
wonder drug. Most studies show only modest benefits from chocolate,
and even though it's good for you, you still have to pay attention to
calories and fat.
"If you ask me what's more important, a little physical activity like
walking or eating the chocolate, go take your walk,'' said Dr. Shani.
"I don't think in the very near future we're going to tell every
patient go ahead and eat lots of chocolate. That would be too good to
be true.''

SOURCE: http://well.blogs.nytimes.com/2007/12/21/the-problem-with-chocolate/?em&ex=11983
86000&en=8bda9317b715368d&ei=5087%0A

Juhana Harju - 24 Dec 2007 05:56 GMT
> In fact, the editors point out that the very thing that
> makes chocolate good for you -- the antioxidants called flavanols -
> also make chocolate taste bitter. As a result, confectionery makers
> often take out the flavanols, stripping the chocolate of its main
> health-promoting properties.

I think that you exaggerate the problem. The so-called Dutch process reduces
bitterness and the amount of flavonoids of chocolate. Still the intake of
common cocoa products is associated with reduced cardiovascular and
all-cause mortality as this study strongly suggests.

Arch Intern Med. 2006 Feb 27;166(4):411-7.
Cocoa intake, blood pressure, and cardiovascular mortality: the Zutphen
Elderly Study.
Buijsse B, Feskens EJ, Kok FJ, Kromhout D.
Center for Nutrition and Health, National Institute for Public Health and
the Environment, Bilthoven, and Division of Human Nutrition, Wageningen
University, Wageningen, the Netherlands.

BACKGROUND: Small, short-term, intervention studies indicate that
cocoa-containing foods improve endothelial function and reduce blood
pressure. We studied whether habitual cocoa intake was cross-sectionally
related to blood pressure and prospectively related with cardiovascular
mortality. METHODS: Data used were of 470 elderly men participating in the
Zutphen Elderly Study and free of chronic diseases at baseline. Blood
pressure was measured at baseline and 5 years later, and causes of death
were ascertained during 15 years of follow-up. Habitual food consumption was
assessed by the cross-check dietary history method in 1985, 1990, and 1995.
Cocoa intake was estimated from the consumption of cocoa-containing foods.
RESULTS: One third of the men did not use cocoa at baseline. The median
cocoa intake among users was 2.11 g/d. After adjustment, the mean systolic
blood pressure in the highest tertile of cocoa intake was 3.7 mm Hg lower
(95% confidence interval [CI], -7.1 to -0.3 mm Hg; P = .03 for trend) and
the mean diastolic blood pressure was 2.1 mm Hg lower (95% CI, -4.0 to -0.2
mm Hg; P = .03 for trend) compared with the lowest tertile. During
follow-up, 314 men died, 152 of cardiovascular diseases. Compared with the
lowest tertile of cocoa intake, the adjusted relative risk for men in the
highest tertile was 0.50 (95% CI, 0.32-0.78; P = .004 for trend) for
cardiovascular mortality and 0.53 (95% CI, 0.39-0.72; P < .001) for
all-cause mortality. CONCLUSION: In a cohort of elderly men, cocoa intake is
inversely associated with blood pressure and 15-year cardiovascular and
all-cause mortality. PMID: 16505260

http://archinte.ama-assn.org/cgi/content/full/166/4/411

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Juhana

Ravintoblogini:
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monty1945@lycos.com - 24 Dec 2007 06:29 GMT
They don't seem to realize that one can simply buy cocoa powder, which
has no fat in it (and is plenty bitter) and make one's own desserts.
Now on to this:

"If you ask me what's more important, a little physical activity like
walking or eating the chocolate, go take your walk..."

This gets to the "crux" of the matter.  Walking is not going to
prevent lipid peroxidation, and if this is the key problem in the
"typical American diet," as the molecular-level evidence suggests,
then it will not help, and might actually do damage (for example, too
much sun exposure to the skin with all the omega 6 or 3 PUFAs in one's
flesh is a true "recipe for disaster."
Ron Peterson - 26 Dec 2007 21:46 GMT
On Dec 24, 12:29 am, monty1...@lycos.com wrote:

> "If you ask me what's more important, a little physical activity like
> walking or eating the chocolate, go take your walk..."

> This gets to the "crux" of the matter.  Walking is not going to
> prevent lipid peroxidation, ...

Fortunately, it does.

http://jap.physiology.org/cgi/content/abstract/64/4/1333 says:
"This study was designed to determine whether endurance training would
influence the production of lipid peroxidation (LI-POX) by-products as
indicated by malondialdehyde (MDA) at rest and after an acute exercise
run. Additionally, the scavenger enzymes catalase (CAT) and superoxide
dismutase (SOD) were examined to determine whether changes in LIPOX
are associated with alterations in enzyme activity both at rest and
after exercise. Male Sprague-Dawley rats (n = 32) were randomly
assigned to either trained or sedentary groups and were killed either
at rest or after 20 min of treadmill running. The training program
increased oxidative capacity 64% in leg muscle. After exercise, the
sedentary group demonstrated increased LIPOX levels in liver and white
skeletal muscle, whereas the endurance-trained group did not show
increases in LIPOX after exercise. CAT activity was higher in both red
and white muscle after exercise in the trained animals. Total SOD
activity was unaffected by either acute or chronic exercise. These
data suggest that endurance training can result in a reduction in
LIPOX levels as indicated by MDA during moderate-intensity exercise.
It is possible that activation of the enzyme catalase and the increase
in respiratory capacity were contributory factors responsible for
regulating LIPOX after training during exercise. "

--
  Ron
monty1945@lycos.com - 26 Dec 2007 22:07 GMT
If a young, healthy person does exercise, the body can adapt and
produce more endogenous antioxidants, but notice how Ron does the
usual, which is to cite one study that appears to support his claim,
while ignoring others.  For example:

http://www.ncbi.nlm.nih.gov/sites/entrez?Db=pubmed&Cmd=ShowDetailView&TermToSear
ch=15643538&ordinalpos=4&itool=EntrezSystem2.PEntrez.Pubmed.Pubmed_ResultsPanel.
Pubmed_RVDocSum


or:
http://www.ncbi.nlm.nih.gov/sites/entrez?Db=pubmed&Cmd=ShowDetailView&TermToSear
ch=16475052&ordinalpos=1&itool=EntrezSystem2.PEntrez.Pubmed.Pubmed_ResultsPanel.
Pubmed_RVAbstractPlus


or:
http://www.ncbi.nlm.nih.gov/sites/entrez?Db=pubmed&Cmd=ShowDetailView&TermToSear
ch=10727077&ordinalpos=1&itool=EntrezSystem2.PEntrez.Pubmed.Pubmed_ResultsPanel.
Pubmed_RVAbstractPlus


or:
http://www.ncbi.nlm.nih.gov/sites/entrez?Db=pubmed&Cmd=ShowDetailView&TermToSear
ch=12486869&ordinalpos=6&itool=EntrezSystem2.PEntrez.Pubmed.Pubmed_ResultsPanel.
Pubmed_RVDocSum


Please, Ron, stop playing these games already !
Mark Thorson - 25 Dec 2007 05:42 GMT
> To boost your chances of getting a flavanol-rich bar, the best bet is
> to look for very dark chocolate with few added ingredients, notes Dr.
[quoted text clipped - 5 lines]
> of flavonoids. A milk chocolate bar contains less than 14 milligrams,
> while white chocolate doesn't have any, according to the Mayo report.

In what sense is the bubble bursting?

It _always_ was about dark chocolate,
not white or milk chocolate.
drlook@drlook.de - 26 Dec 2007 10:30 GMT
> In what sense is the bubble bursting?
>
> It _always_ was about dark chocolate,
> not white or milk chocolate.

exactly, I cannot aggreee more. The headline or title, ."... the
chocolate bubble is bursting"
is absolute hyper nonsense.
Taka - 26 Dec 2007 14:07 GMT
On Dec 26, 7:30 pm, drl...@drlook.de wrote:
> > In what sense is the bubble bursting?
>
[quoted text clipped - 4 lines]
> chocolate bubble is bursting"
> is absolute hyper nonsense.

You did not read it right, the chocolate is still dark but without the
flavonols even if it tastes bit bitter ...  I don't know by which
process they are reducing them during the manufacture, this was just
news in several newspapers in different countries recently.

Taka
Juhana Harju - 26 Dec 2007 17:49 GMT
> On Dec 26, 7:30 pm, drl...@drlook.de wrote:
>>> In what sense is the bubble bursting?
[quoted text clipped - 10 lines]
> process they are reducing them during the manufacture, this was just
> news in several newspapers in different countries recently.

It appears that you are confusing two different things. In the recent
chocolate study the control group was given _cocoa-free_ chocolate:

http://www.tinyurl.dk/2618

On the other hand, the so-called Dutch process reduces the amount of
flavanols in common cocoa products, but does not completely destroy them.

Signature

Juhana

Ravintoblogini:
http://ruohikolla.blogspot.com/

Taka - 27 Dec 2007 03:34 GMT
> On the other hand, the so-called Dutch process reduces the amount of
> flavanols in common cocoa products, but does not completely destroy them.

Yes, the "Dutch process" is what I had on my mind.  Do you have any
references to it?  I am wondering whether we can simply judge how much
flavanols have been removed by the degree of bitter taste.  BTW I have
been eating 72% cacao Carrefour chocolate for quite a while but it
doesn't taste bitter neither is too sweet.

Taka
Mark Thorson - 27 Dec 2007 03:57 GMT
> > On the other hand, the so-called Dutch process reduces the amount of
> > flavanols in common cocoa products, but does not completely destroy them.
[quoted text clipped - 4 lines]
> BTW I have been eating 72% cacao Carrefour chocolate for quite a
> while but it doesn't taste bitter neither is too sweet.

I think what you want is lightly roasted cocoa nibs,
as used in bars from Scharffen-Berger, Valrhona, and
Chocovic.

Of course, if you eat chocolate for purely health
reasons, without regard to other factors, you
probably want this crap:

http://www.cocoavia.com/faq.aspx

Before you ask, no I haven't tried it.  Any chocolate
optimized for health couldn't possibly be a good
chocolate.  Besides which, it contains soy protein,
and I have a soy protein sensitivity.  I can't eat
this product without risk.
Pramesh Rutaji - 27 Dec 2007 04:25 GMT
>>> On the other hand, the so-called Dutch process reduces the amount of
>>> flavanols in common cocoa products, but does not completely destroy them.
[quoted text clipped - 19 lines]
> and I have a soy protein sensitivity.  I can't eat
> this product without risk.

I use the following.  It doesn't use the Dutch process and is 100% raw organic
cocoa grown and harvested under "Fair Trade" practices and the process never
takes the temperature above 110%.  I make hot cocoa every morning using stevia
to sweeten - I heat the water to 120 degrees.

Navitas Naturals Raw Chocolate Powder, Organic, 16-Ounce Bags
http://www.amazon.com/Navitas-Naturals-Chocolate-Organic-16-Ounce/dp/B000P24HJ8/
ref=pd_bbs_1?ie=UTF8&s=grocery&qid=1198728985&sr=8-1

http://www.iherb.com/ProductDetails.aspx?c=1&pid=8254&at=0

--

Pramesh
Ted - 27 Dec 2007 17:40 GMT
On Dec 26, 11:25 pm, Pramesh Rutaji <p297tongue6...@newsguy.com>
wrote:
> >>> On the other hand, the so-called Dutch process reduces the amount of
> >>> flavanols in common cocoa products, but does not completely destroy them.
[quoted text clipped - 30 lines]
>
> Pramesh

Hey thanks for that. Do you know how much is required to get some
benefit? Is 1 serving a day enough?
Pramesh Rutaji - 29 Dec 2007 19:01 GMT
> On Dec 26, 11:25 pm, Pramesh Rutaji <p297tongue6...@newsguy.com>
> wrote:
[quoted text clipped - 30 lines]
> Hey thanks for that. Do you know how much is required to get some
> benefit? Is 1 serving a day enough?

I've seen the number placed at about 28 grams/one oz. per day.  I personally use
about 0.75 oz a day and also get cocoa extract from taking lef.org products that
contain it.

Pramesh
Mark Thorson - 27 Dec 2007 19:41 GMT
> I use the following.  It doesn't use the Dutch process and is 100% raw
> organic cocoa grown and harvested under "Fair Trade" practices and the
> process never takes the temperature above 110%.  I make hot cocoa every
> morning using stevia to sweeten - I heat the water to 120 degrees.

That reminds me, you can find raw cacao beans
in many Mexican food stores.  They are fermented,
but not roasted.  (Actually, you'll find a few
unfermented beans in each bag.)

A peeled raw cacao bean tastes very good, like
a piece of 99% dark chocolate.  The occasional
unfermented bean has very little flavor.  An
unfermented bean is off-white, like a cashew nut,
while the fermented beans are dark purplish brown.
Thomas Carter - 28 Dec 2007 06:18 GMT
> > I use the following. �It doesn't use the Dutch process and is 100% raw
> > organic cocoa grown and harvested under "Fair Trade" practices and the
[quoted text clipped - 11 lines]
> unfermented bean is off-white, like a cashew nut,
> while the fermented beans are dark purplish brown.

Hi,

About 4 gms of cocoa in the Zutphen study of elderly men resulted in
about a 50% reduction in mortality. Half of this was dark and half was
milk chocolaate which has only about a fourth of the polyphenols. The
men got it by eating candy, so they probably took it once a day or
less. The half life  of the polyphenols is short, so divided doses
should be better. PMID: 16505260

And indeed the Kuna Indians of Panama that were age 50 or above
experienced over a 95% reduction in cancer and cardiovascular
fatalities along with a 70% reduction in total mortallity compared to
mainland Panamanians. They averaged 900 mg of polyphenols which they
got in five cups of a cocoa beverage plus some in other recipes.  They
died mostly of infections and respiratory diseases due to extreme
poverty and lack of health care. PMID: 17299579, PMID: 16794463.

These data strongly indicate that very hi levels in divided doses are
immensely potent and give additive benefits to other aspects of
healthy lifestyles shared by the Kunas and life extensionists. They
also explain the extreme recent interest in the issue on the part of
academia, the Hershey co., and less importantly yours truely.

Thomas
Thomas Carter - 28 Dec 2007 06:26 GMT
> > > I use the following. �It doesn't use the Dutch process and is 100% raw
> > > organic cocoa grown and harvested under "Fair Trade" practices and the
[quoted text clipped - 38 lines]
>
> - Show quoted text -

Hi Thomas,

Why didn't you post a guide for getting hi polyphenol levels?

Thomas

             Unfermented, sun dried beans have        8% polyphenols
             Undermented, roasted beans have          5% polyphenols
             Fermented, sun dried beans have           4% polyphenols
     Fresh, or fermented and roasted beans have  2%
polyphenols
                PMID: 17439235
soowhatdouthink@hotmail.com - 29 Dec 2007 22:13 GMT
> > I use the following.  It doesn't use the Dutch process and is 100% raw
> > organic cocoa grown and harvested under "Fair Trade" practices and the
[quoted text clipped - 11 lines]
> unfermented bean is off-white, like a cashew nut,
> while the fermented beans are dark purplish brown.

I got hooked on the taste of whole unfermented cocoa beans (bought
from an Internet site).  Mixing in warm water -- ground beans with a
very tasty 99% Pernigotti cocoa powder (dutched) 3:1 respectively,
sweetened with 1/2 teaspoon of ground cinnamon bark and add very
little milk- gives a bitter but delicious drink!
As you said, fermented whole cocoa beans should taste chocolatier but
I have not found any site that sells them.  How do you know that the
beans you buy in the Mexican store are fermented (since they are whole
beans, at least you can be sure that they aren't roasted or they would
be nibs;-)?  In fact, all dried cocoa beans are fermented to a certain
degree (very little), which happens from the time the fruit is picked
until the beans are dried.  But this isn't long enough to be fully
fermented as it happens with beans are used for all commercial cocoa
products - where the cocoa beans are left in the cocoa fruits are left
to ferment before they are roasted.

Arbor
Mark Thorson - 30 Dec 2007 19:32 GMT
> As you said, fermented whole cocoa beans should taste chocolatier but
> I have not found any site that sells them.  How do you know that the
> beans you buy in the Mexican store are fermented (since they are whole

By color.  Unfermented beans are about the same color
as a cashew.  Fermented beans are dark brown.  Also,
by flavor.  Unfermented beans do not taste at all
like chocolate.

> beans, at least you can be sure that they aren't roasted or they would
> be nibs;-)?  In fact, all dried cocoa beans are fermented to a certain
[quoted text clipped - 3 lines]
> products - where the cocoa beans are left in the cocoa fruits are left
> to ferment before they are roasted.

Fermentation occurs as an explicit step in cacao
processing.  The pods are opened, the beans and
flesh are scooped out, and they are placed in boxes
to ferment.  During fermentation, the color changes
and the chocolate flavor develops.  This also aids
removal of the flesh from the beans.
soowhatdouthink@hotmail.com - 30 Dec 2007 22:19 GMT
Mark wrote:
>During fermentation, the color changes
> and the chocolate flavor develops.  This also aids
> removal of the flesh from the beans.

Mark,
Comments:

1.    While fermentation is an important step toward the final chocolaty
taste that we all know, fully fermented beans are far from tasting
chocolaty OR the roasting and dutching processes wouldn't be
necessary.  In fact, for most people even undutched cocoa powder, is
not acceptable let alone cocoa nibs that come from fully fermented
roasted beans.
2.    All selling sites sell either lightly fermented beans or roasted
fully fermented nibs and the question is why, why they don't sell
fully fermented beans?  The reason is that fermentation is probably
the most delicate and problematic stage on the way from the pod to the
end product.  The problems are reviewed in [1] below.  Large cocoa end-
product producers (like Mars, Hershey and others) in Western countries
have the means and the expertise for quality control but that is not
the case with importers of beans that sold on the Internet. The safest
product that one can get from these sellers is the lightly fermented
and maybe the nibs.  With the lightly fermented beans it's easy to
spot discoloration (due to mold or disease), and the integrity of each
bean.  Again, even nibs don't have the chocolaty taste let alone
expecting it from fully fermented whole beans.
3.    Currently, the biggest company that I have spotted on the Internet
is Navitas (I have no affiliation with the company whatsoever) that
one can buy even from Amazon's site.  The best price for Navitas
(beans from Ecuador) currently (I think) is from iherb.com.  As
explained in the below website- short of getting beans from Mars or
Hershey;-) there are advantages for buying from a big identified
importer and a reputable websites.
4.    Therefore for now my solution is to mix dutched cocoa powder that
one likes with - for taste with ground whole beans for polyphenols and
reduced lead contents

1.    http://www.tis-gdv.de/tis_e/ware/genuss/kakao/kakao.htm
Other interesting sites:
2.    http://www.tava.com.au/article_processing.html
3.    http://www.cocoatree.org/frombeantobar/harvestingcocoabeans.asp

Arbor
Mark Thorson - 30 Dec 2007 22:55 GMT
> 1.      While fermentation is an important step toward the final
> chocolaty taste that we all know, fully fermented beans are far
> from tasting chocolaty OR the roasting and dutching processes
> wouldn't be necessary.

I take it you've never had fermented, unroasted cacao?
Juhana Harju - 27 Dec 2007 04:30 GMT
>> On the other hand, the so-called Dutch process reduces the amount of
>> flavanols in common cocoa products, but does not completely destroy
>> them.
>
> Yes, the "Dutch process" is what I had on my mind.  Do you have any
> references to it?

J Agric Food Chem. 2006 May 31;54(11):4057-61.
Procyanidin and catechin contents and antioxidant capacity of cocoa and
chocolate products.
Gu L, House SE, Wu X, Ou B, Prior RL.
Arkansas Children's Nutrition Center, ARS-USDA, and Department of Physiology
and Biophysics, University of Arkansas for Medical Sciences, Little Rock,
Arkansas 72202, USA.

Cocoa and chocolate products from major brands were analyzed blind for total
antioxidant capacity (AOC) (lipophilic and hydrophilic ORAC(FL)), catechins,
and procyanidins (monomer through polymers). Accuracy of analyses was
ascertained by comparing analyses on a NIST standard reference chocolate
with NIST certified values. Procyanidin (PC) content was related to the
nonfat cocoa solid (NFCS) content. The natural cocoa powders (average 87% of
NFCS) contained the highest levels of AOC (826 +/- 103 micromol of TE/g) and
PCs (40.8 +/- 8.3 mg/g). Alkalized cocoa (Dutched powders, average 80% NFCS)
contained lower AOC (402 +/- 6 micromol of TE /g) and PCs (8.9 +/- 2.7
mg/g). Unsweetened chocolates or chocolate liquor (50% NFCS) contained 496
+/- 40 micromol of TE /g of AOC and 22.3 +/- 2.9 mg/g of PCs. Milk
chocolates, which contain the least amount of NFCS (7.1%), had the lowest
concentrations of AOC (80 +/- 10 micromol of TE /g) and PCs (2.7 +/- 0.5
mg/g). One serving of cocoa (5 g) or chocolate (15 or 40 g, depending upon
the type of chocolate) provides 2000-9100 micromol of TE of AOC and 45-517
mg of PCs, amounts that exceed the amount in a serving of the majority of
foods consumed in America. The monomers through trimers, which are thought
to be directly bioavailable, contributed 30% of the total PCs in chocolates.
Hydrophilic antioxidant capacity contributed >90% of AOC in all products.
The correlation coefficient between AOC and PCs in chocolates was 0.92,
suggesting that PCs are the dominant antioxidants in cocoa and chocolates.
These results indicate that NFCS is correlated with AOC and PC in cocoa and
chocolate products. Alkalizing dramatically decreased both the procyanidin
content and antioxidant capacity, although not to the same extent. PMID:
16719534

http://www.tinyurl.dk/2628

> I am wondering whether we can simply judge how much
> flavanols have been removed by the degree of bitter taste.  BTW I have
> been eating 72% cacao Carrefour chocolate for quite a while but it
> doesn't taste bitter neither is too sweet.

I am not familiar with the product. Perhaps you should ask the manufacturer
if you want to know whether its cocoa has been Dutched.

Signature

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Ravintoblogini:
http://ruohikolla.blogspot.com/

 
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